Water Layer Research Articles

Venus water loss is dominated by HCO+ dissociative recombination.

Despite its Earth-like size and source material1,2, Venus is extremely dry3,4, indicating near-total water loss to space by means of hydrogen outflow from an ancient, steam-dominated atmosphere5,6. Such hydrodynamic escapelikely removed most of an initial Earth-like 3-km global equivalent layer (GEL) of water but cannot deplete the atmosphere to the observed 3-cm GEL because it shuts down below about 10-100 m GEL5,7. To complete Venus water loss, and to produce the observed bulk atmospheric enrichment in deuterium of about 120 times Earth8,9, nonthermal H escape mechanisms still operating today are required10,11. Early studies identified these as resonant charge exchange12-14, hot oxygen impact15,16 and ion outflow17,18, establishing a consensus view of H escape10,19 that has since received only minimal updates20. Here we show that this consensus omits the most important present-day H loss process, HCO+ dissociative recombination. This process nearly doubles the Venus H escape rate and, consequently, doubles the amount of present-dayvolcanic water outgassing and/orimpactor infall required to maintain a steady-state atmospheric water abundance. These higher loss rates resolve long-standing difficulties in simultaneously explaining the measured abundance and isotope ratio of Venusian water21,22 and would enable faster desiccation in the wake of speculative late ocean scenarios23. Design limitations prevented past Venus missions from measuring both HCO+ and the escaping hydrogen produced by its recombination; future spacecraft measurements are imperative.

Reconfigurable water-based metamaterial with hybrid mechanism for backward-scattering reduction

Abstract A hybrid mechanism water-based metamaterial (HMWM) with polarization conversion, absorption and phase cancellation mechanisms is proposed in this paper. The absorption and polarization conversion mechanisms are integrated by combining the water layer with polarization conversion structure, and the absorption conversion rate (ACR) reaches more than 90% in the dual band (4.0-4.7 GHz and 8.2-15.7 GHz). Based on the above mechanism, the phase cancellation mechanism makes use of the opposite phase between HMWM and its mirror structure for checkerboard configuration to reduce the wideband radar cross section (RCS) by 3-18 GHz, achieving wide-angle RCS reduction and polarization insensitivity. In addition, the model realizes stealth control by adjusting RCS reduction capability under different water layer conditions. The results of simulation and experiment agree well, which fully demonstrates that the HMWM has scattering suppression capability and has potential application in multifunctional metamaterial.

Membrane-Bound Ferric Hemoglobin in Nucleated Erythrocytes of the Black Scorpionfish Scorpaena porcus, Linnaeus 1758.

The content of membrane-bound methemoglobin (MtHb) in nucleated erythrocytes was studied in the black scorpionfish Scorpaena porcus (Linnaeus, 1758) in vitro. Spectral characteristics were determined for a whole hemolysate, a hemolysate obtained by stroma precipitation (a clarified hemolysate), and a resuspended stroma. The MtHb proportion in the erythrocyte stroma was found to exceed 80% (6.20 ± 0.59 µM). Clarified hemolysates were nearly free of MtHb (0.5 ± 0.2 µM). Membrane-bound ferric hemoglobin did not affect the erythrocyte resistance to osmotic shock. The osmotic fragility range was determined using a LaSca-TM laser microparticle analyzer (BioMedSystems, Russia) to be 102-136 mOsm/kg, much the same as in other bony fish species. A nitrite load (10 mg/L) significantly increased the MtHb content in the blood. However, the membrane-bound ferric hemoglobin content did not change significantly, amounting to 6.34 ± 1.09 µM (approximately 95%). The finding suggested a functional importance for MtHb present in the plasma membrane of nucleated erythrocytes. Membrane-bound MtHb was assumed to neutralize the external oxidative load and the toxic effect of hydrogen sulfide in bottom water layers, where the species lives.

Cholesterol Changes Interfacial Water Alignment in Model Cell Membranes.

The nanoscopic layer of water that directly hydrates biological membranes plays a critical role in maintaining the cell structure, regulating biochemical processes, and managing intermolecular interactions at the membrane interface. Therefore, comprehending the membrane structure, including its hydration, is essential for understanding the chemistry of life. While cholesterol is a fundamental lipid molecule in mammalian cells, influencing both the structure and dynamics of cell membranes, its impact on the structure of interfacial water has remained unknown. We used surface-specific vibrational sum-frequency generation spectroscopy to study the effect of cholesterol on the structure and hydration of monolayers of the lipids 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC), 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC), and egg sphingomyelin (SM). We found that for the unsaturated lipid DOPC, cholesterol intercalates in the membrane without significantly changing the orientation of the lipid tails and the orientation of the water molecules hydrating the headgroups of DOPC. In contrast, for the saturated lipids DPPC and SM, the addition of cholesterol leads to clearly enhanced packing and ordering of the hydrophobic tails. It is also observed that the orientation of the water hydrating the lipid headgroups is enhanced upon the addition of cholesterol. These results are important because the orientation of interfacial water molecules influences the cell membranes' dipole potential and the strength and specificity of interactions between cell membranes and peripheral proteins and other biomolecules. The lipid nature-dependent role of cholesterol in altering the arrangement of interfacial water molecules offers a fresh perspective on domain-selective cellular processes, such as protein binding.

Inversion of Stabilized Large Droplet Clusters.

We investigate the spontaneous rearrangement of microdroplets in a self-assembled droplet cluster levitating over a thin locally heated water layer. The center-to-periphery droplet diameter ratio (the "inversion coefficient") controls the onset of the inversion. Larger droplets can squeeze between smaller ones due to increased drag force on them from the air-vapor flow. In smaller clusters, the rotation of the droplets plays an important role since larger droplets rotating with the same angular velocity (dependent on the rotor of the airflow field) have higher viscous friction force with the liquid layer. It is desirable to avoid cluster inversion in experiments where individual droplet positions should be traced.

Transcriptomic insights into the dominance of two phototrophs throughout the water column of a tropical hypersaline-alkaline crater lake (Dziani Dzaha, Mayotte)

Saline-alkaline lakes often shelter high biomasses despite challenging conditions, owing to the occurrence of highly adapted phototrophs. Dziani Dzaha (Mayotte) is one such lake characterized by the stable co-dominance of the cyanobacterium Limnospira platensis and the picoeukaryote Picocystis salinarum throughout its water column. Despite light penetrating only into the uppermost meter, the prevailing co-dominance of these species persists even in light- and oxygen-deprived zones. Here, a depth profile of phototrophs metatranscriptomes, annotated using genomic data from isolated strains, is employed to identify expression patterns of genes related to carbon processing pathways including photosynthesis, transporters and fermentation. The findings indicate a prominence of gene expression associated with photosynthesis, with a peak of expression around 1 m below the surface, although the light intensity is very low and only red and dark red wavelengths can reach it, given the very high turbidity linked to the high biomass of L. platensis. Experiments on strains confirmed that both species do grow under these wavelengths, at rates comparable to those obtained under white light. A decrease in the expression of photosynthesis-related genes was observed in L. platensis with increasing depth, whereas P. salinarum maintained a very high pool of psbA transcripts down to the deepest point as a possible adaptation against photodamage, in the absence and/or very low levels of expression of genes involved in protection. In the aphotic/anoxic zone, expression of genes involved in fermentation pathways suggests active metabolism of reserve or available dissolved carbon compounds. Overall, L. platensis seems to be adapted to the uppermost water layer, where it is probably maintained thanks to gas vesicles, as evidenced by high expression of the gvpA gene. In contrast, P. salinarum occurs at similar densities throughout the water column, with a peak in abundance and gene expression levels which suggests a better adaptation to lower light intensities. These slight differences may contribute to limited inter-specific competition, favoring stable co-dominance of these two phototrophs.

Recent records of thermohaline profiles and water depth in the Taam ja’ Blue Hole (Chetumal Bay, Mexico)

Coastal karst structures have been recently explored and documented in Chetumal Bay, Mexico, at the southeast of the Yucatan Peninsula. These structures, recognized as blue holes, stand out for their remarkable dimensions within a shallow estuarine environment. Particularly the Taam Ja’ Blue Hole (TJBH), revealed a depth of ~274 mbsl based on echo sounder mapping, momentarily positioning it as the world's second-deepest blue hole. However, echo sounding methods face challenges in complex environments like blue holes or inland sinkholes arising from frequency-dependent detection and range limitations due to water density vertical gradients, cross-sectional depth variations, or morphometric deviations in non-strictly vertical caves. Initial exploration could not reach the bottom and confirm its position, prompting ongoing investigation into the geomorphological features of TJBH. Recent CTD profiler records in TJBH surpassed 420 mbsl with no bottom yet reached, establishing the TJBH as the deepest-known blue hole globally. Hydrographic data delineated multiple water layers within TJBH. Comparison with Caribbean water conditions at the Mesoamerican Barrier Reef System, reef lagoons, and estuaries suggests potential subterranean connections. Further research and implementation of underwater navigation technologies are essential to decipher its maximum depth and the possibilities of forming part of an interconnected system of caves and tunnels.

Temperature Structure Inversion of Mesoscale Eddies in the South China Sea Based on Deep Learning

Mesoscale eddies are common in global oceans, playing crucial roles in ocean dynamics, ocean circulation, and heat transport, and their vertical structures can affect the water layers from tens to thousands of meters. In this study, we integrated sea surface height and sea surface temperature data into deep learning methods to study the mesoscale eddy subsurface temperature structure and to explore the relationship between sea surface data and eddy subsurface layers. In this study, we introduce Dual_EddyNet, a deep learning algorithm designed to invert the subsurface temperature structure of mesoscale eddies. Using this algorithm, we explore the impact of the sea surface height and sea surface temperature on the subsurface temperature structure inversion of mesoscale eddies. Furthermore, we compare different data fusion strategies, namely single-stream neural networks and dual-stream neural networks, to validate the effectiveness of the dual-stream model. To capture the interrelations among surface data and integrate feature information across various dimensions, we introduce the Triplet Attention Mechanism. The experimental results demonstrate that the proposed Dual_EddyNet performs well in reconstructing the three-dimensional structure of mesoscale eddies in the South China Sea (within a depth of 1000 m), with an inversion accuracy of 91.44% for cyclonic eddies and 95.25% for anticyclonic eddies. This algorithm provides a new method for inverting the subsurface temperatures of mesoscale eddies, and can not only be directly deployed in systems, embedded in ship moving platforms, etc., but can also provide a data reference for assimilations and numerical simulations, demonstrating its rich application potential.

Calibration of horizontal seismic design spectra of offshore earthquake ground motions by applying improved differential evolution method

Design Response Spectrum (DRS) serves as a crucial cornerstone for seismic design, encapsulating the characteristic parameters of the design spectrum. To investigate the offshore design spectrum required for seismic design of offshore structures, improved differential evolution (DE) methods are first used to determine the characteristic parameters of the horizontal design spectra of offshore ground motions. In assessing the stability and precision of the chosen improved DE methods, we scrutinize the applicability of various renowned DE methodologies in the calibration process. Our findings indicate that differential evolution with global and local neighborhoods (GLDE) exhibits superior stability and accuracy compared to other DE methods, rendering it suitable for calibrating the design spectrum to delineate optimal characteristic parameters of the DRS. Subsequently, the properties of the offshore horizontal design spectra are investigated by applying the recommended GLDE to 6756 seismic data collected from three offshore regions. The site conditions of water depth and sedimentary thickness of the ocean-bottom stations were investigated by the finely divided seismic data with classified earthquake types. The ocean-bottom stations are classified as A-D by the water depth and sedimentary thickness, and the offshore DRS for four site classes with different earthquake types are presented in this study. According to the observed offshore response spectra with different water depth groups, it is found that the water depth should be considered in the offshore design spectra mainly due to the differences between buried and unburied seafloor stations, and the spectral values with deep water layer are considerably larger than those with shallow water. Offshore DRSs are compared with onshore DRSs of seismic codes and different peak ground acceleration (PGA) groups are presented in this study.

Subsurface stratigraphy suggested by the layered ejecta craters in the Martian northern planitiae

The formation of layered ejecta craters (LECs) is generally thought to be related to the subsurface water-ice. The distribution of LECs in the northern regions of Mars (0 to 70° N) features both local and latitudinal variations, e.g., there are generally few LECs within volcanic areas, and the observed minimum and median diameters of the LECs decreases with increasing latitude. The observed minimum diameters of the LECs in the six planitiae within the northern lowlands suggest the roof depth of the LECs-forming layer has clear lateral variability, ranging between ∼90 m in the Arcadia Planitia and ∼280 m in the Isidis Planitia. The observed LECs are suggested to mainly form during the Amazonian, implying that the LEC-forming water-ice-bearing strata might be still present. The variation might reflect the comprehensive influence on the subsurface water-ice by the climate conditions and geologic events during the Amazonian period. The proposed subsurface stratigraphies in the six planitiae suggest that the total thickness of the LECs-related strata in the Chryse Planitia is the largest (∼4.6 km) and in the Arcadia Planitia is the smallest (∼1.6 km). There could be as much as ∼3.5–16 million km3 subsurface water stored in these strata, resulting in a ∼24–110 m global equivalent layer (GEL) of water. Given that water is a fundamental ingredient to life, its migration from surface to subsurface shifts the focus of its exploration. Both Arcadia and Utopia Planitiae represent ideal candidates as locations where both shallow and deep subsurface water-ice might be abundant, they represent high-priority targets for future missions at mid-latitudes for biosignature searching and in-situ resource utilization.

Dissolution of gas in a stationary liquid layer: A diffusion-kinetic model and experimental studies

An analytic model of gas dissolution in a stationary liquid layer is presented. This model considers for the first time the intrinsic kinetics of the process of gas dissolution in a liquid characterized by the rate of gas absorption/desorption reaction at the gas–liquid interface. Within the framework of the presented model, it is shown that the process of gas dissolution in a stationary liquid layer occurs either in the diffusion-kinetic regime or in the diffusion regime. In the diffusion-kinetic regime, the rate of gas dissolution in a stationary liquid layer is affected by both the intensity of gas diffusion through the liquid layer and the intrinsic kinetics of the gas dissolution process in the liquid; in the diffusion regime, the rate of gas dissolution in a stationary liquid layer is limited only by the intensity of gas diffusion through the liquid layer. Experiments were carried out to study the kinetics of methane dissolution in a stationary layer of water at different temperatures. From the comparison of calculated and experimental data, the values of the diffusion coefficient of methane in water were determined, and it was also established that the process of methane dissolution in a stationary layer of water occurs in the diffusion regime. A new empirical correlation for calculating the diffusion coefficient of methane in water in the temperature range from 273 to 323.15 K was obtained based on our and available data points: D[m2/s]=exp(−12.64−2250.5/T[K]).

Capillary Condensation of Water in Graphene Nanocapillaries.

Recent experiments have revealed that the macroscopic Kelvin equation remains surprisingly accurate even for nanoscale capillaries. This phenomenon was so far explained by the oscillatory behavior of the solid-liquid interfacial free energy. We here demonstrate thermodynamic and capillarity inconsistencies with this explanation. After revising the Kelvin equation, we ascribe its validity at nanoscale confinement to the effect of disjoining pressure. To substantiate our hypothesis, we employed molecular dynamics simulations to evaluate interfacial heat transfer and wetting properties. Our assessments unveil a breakdown in a previously established proportionality between the work of adhesion and the Kapitza conductance at capillary heights below 1.3 nm, where the dominance of the work of adhesion shifts primarily from energy to entropy. Alternatively, the peak density of the initial water layer can effectively probe the work of adhesion. Unlike under bulk conditions, high confinement renders the work of adhesion entropically unfavorable.

Surface water oxygenation and low bioproductivity during deposition of iron formation of the Jacadigo Group (Brazil): Insights from combined cadmium – Chromium isotopes

The Banda Alta Formation (Urucum district, Mato Grosso do Sul, Brazil) comprises ∼600 Ma Fe and Mn deposits, which are among the world's youngest and largest Neoproterozoic sedimentary Fe and Mn formations (IF; MnF). These have been deposited in a redox-stratified, marine sub-basin (Jacadigo Basin), which was strongly influenced by glacial advance/retraction cycles with temporary influx of continental freshwater and upwelling of metal-enriched deep anoxic seawater. Cr and Cd isotopes measured on meticulously separated hematite mesobands from drill core samples are relatively homogenous throughout the ca. 325 m thick sequence sampled in the Banda Alta Fm., with average authigenic δ53Cr values of +0.93 ± 0.24 ‰ (2σ; n = 23) and δ114Cd values of −0.14 ± 0.14 ‰ (2σ; n = 15). The significant enrichment of Cr, in parallel with the strong enrichments of other redox sensitive elements (U, Mo), attests for effective and efficient reduction removal processes in the surface waters during cycles where upwelling Fe2+-rich waters reached the oxygenated surface layer exposed to the atmosphere during episodic glacier retreat stages. Assuming a similar quantitative and efficient removal pathway of dissolved Cd by iron oxyhydroxides, the so-inferred average δ114Cd signature of −0.14 ± 0.14 ‰ in the Jacadigo Basin surface water is significantly lower than signatures of modern ocean surface waters with a range of δ114Cd of ca. ∼0.4 to ∼1 ‰ and even lower than the signature of modern ocean deep waters with δ114Cd of ∼0.3 ‰. It possibly attests to reduced primary production levels and lower nutrient utilization rates during deposition of the Late Neoproterozoic Jacadigo Group, compared to today. This despite the inferred oxidized surface water layer that must have prevailed during this time, as implied by the strongly positively fractionated Cr isotope signatures and pronouncedly negative Ce-anomalies recorded in the seawater-like, shale-normalized Rare Earth Element and Yttrium (REY) patterns exhibited by the hematite mesobands. Data presented herein speak for: (1) a stable, isotopically heavy Cr input to the Jacadigo Basin at the time of deposition, implying high atmospheric O2 levels in the Late Neoproterozoic (2) likely quantitative, reductive incorporation / adsorption processes of dissolved Cr and Cd, respectively, into/onto precipitating iron oxyhydroxides, and (3) the prevalence of low nutrient concentrations and utilization rates in the Jacadigo Basin during glacier retreat cycles. Banded iron formations are considered suitable archives for reconstructing redox and bioproductivity levels in past marine depositional basin, including those prevalent in Neoproterozoic glacial conditions, via employing the CrCd isotope double tracer to iron-rich mesobands.

Ambiguous Faces of Water-Based Inclusion Compounds: L4(4)8(8) Intercalato-Clathrate Hydrate of Pt(II) Complex.

Clathrate hydrates are among the most intensively studied H-bond inclusion compounds. Despite the broad definition for this class of compounds, their meaning commonly refers to closed polyhedral nanocages that encapsulate small guest molecules. On the other hand, larger solutes enforce another type of encapsulation because of the solute size effect. Herein, we report a series of structures containing various molecules encapsulated by intercalated water layers constructed of polycyclic moieties of L4(4)8(8) topology. We parametrized the corrugation of individual layers and characterized interactions governing their formation. We suggested which could be categorized as two-dimensional clathrates based on the character of intra-layer interactions and effects observed between entrapped molecules and water-based intercalators.

1300-m-High gas plume from pockmarks in the north Nansha waters, South China sea

The northeastern region of Nansha Waters, located in the southern margin of the South China Sea, is abundant in gas resources. However, it remains unclear if the central and northern areas of Nansha Waters possess gas resources and if there are any associated leaks. The Jiuzhang Basin is located in the northern Nansha Waters. Pre-stack depth migration, analysis of seismic attributes and multibeam data processing were conducted to image the seabed topography and backscatter intensity, as well as the seismic structure of the water and sedimentary layers in the Jiuzhang Basin. The result reveals a presence of large plumes, approximately 1500 m in width and up to 1300 m in height, from a pockmark. The plume is characterized by a strong seismic amplitude featuring chaotic reflections, a high instantaneous frequency (100–150 Hz), and a strong instantaneous amplitude. These seismic features commonly appear in hydrocarbon-bearing seawater, indicating that the plume is composed of gas. The relationship between the volume fraction of bubbles in the gas plumes and the amplitude of multi-channel seismic waves suggests that the volume fraction of bubbles within the gas plume can reach up to 5.0 × 10−3. Meanwhile, a new pockmark with a length of 248 m, a width of 90 m, and a depth of 20.4 m, and an abrupt 22 m drop in water depth of an existing pockmark are observed in the gas plume area. These observations, combined with the gas plume revealed by the multi-channel seismic collected in 2013 and multibeam collected in 2020, suggest a very strong and recently active gas leaks in the pockmark area of the northern Jiuzhang Basin. Furthermore, in the pockmark area, there are gas-bearing formations with weak reflections, and mud diapirs charactered by low seismic velocity, low amplitude chaotic reflections, and pulled up reflections on both sides, and faults extend to the seabed. These observations suggest that gas plume originate from deep strata of the northern Jiuzhang Basin. Large gas plumes and mud diapirs are often indicative of the existence of deep gas reservoirs. Therefore, the presence of such active gas plumes and mud diapirs in the northern region of the Jiuzhang Basin signifies the presence of abundant gas resources.

HYDROPLANING OF TIRES: A REVIEW OF NUMERICAL MODELING AND NOVEL SENSING METHODS

Abstract This article represents an extensive literature on tire hydroplaning, specifically focusing on the assessment of real-time estimation methodologies and numerical modeling for both partial and total hydroplaning phenomenon. Hydroplaning still poses a significant challenge for contemporary passenger cars, even those equipped with state of the art safety systems. The active safety features that equip the most technologically advanced passenger cars are unable to forecast and prevent the occurrence of hydroplaning. Total hydroplaning represents a phenomenon which occurs when the tire reaches a point where it can no longer expel the water from its tread grooves, leading to a complete control loss of the motor vehicle. This describes a scenario in which the entire contact patch is lifted from the ground due to the hydrodynamic forces generated at the contact between the tire and the layer of water formed on the road. Nevertheless, the decrease in contact between the tire and the road surface occurs gradually, a phenomenon which is presented in literature as partial hydroplaning. The longitudinal speed that marks the transition from partial hydroplaning to total hydroplaning is defined as the critical hydroplaning speed. These principles are widely acknowledged among researchers in the hydroplaning field. Nonetheless, the literature review reveals variations for defining the critical hydroplaning speed threshold across different experimental investigations. In this article, past studies, and state-of-the-art research on tire hydroplaning has been reviewed, especially focusing on real-time estimation methodologies and numerical modeling of the partial and of the total hydroplaning phenomenon.

Combined effects of pH and dissolved organic matter on the availability of pharmaceuticals and personal care products in aqueous environment

The interaction between pharmaceuticals and personal care products (PPCPs) with dissolved organic matter (DOM) can alter their bioavailability and toxicity. Nevertheless, little is known about how pH and DOM work together to affect the availability of PPCPs. This study investigated the impact of pH and DOM on the availability of seven PPCPs, namely Carbamazepine, Estrone, Bisphenol A, Testosterone Propionate, Triclocarban, 4-tert-Octylphenol and 4-n-Nonylphenol, using negligible depletion solid-phase microextraction (nd-SPME). The uptake kinetics of PPCPs by the nd-SPME fibers increased proportionally with DOM concentrations, likely due to enhanced diffusive conductivity in the unstirred water layer. At neutral pH, the partitioning coefficients of PPCPs for Humic Acid (log KDOC 3.87–5.25) were marginally higher than those for Fulvic Acid (log KDOC 3.64–5.11). Also, the log KDOC values correlated linearly with the log DOW (pH 7.0) values of PPCPs, indicating a predominant role for hydrophobic interactions in the binding of DOM and PPCPs. Additionally, specific interactions like hydrogen bonding, π-π, and electrostatic interactions occur for certain compounds, influenced by the polarity and spatial conformation of the compounds. For these ionizable PPCPs, the log DDOC values exhibit a strong dependence on pH due to the dual influence of pH on both DOM and PPCPs. The log DDOC values rose from pH 1.0 to 3.0, peaked at pH 5.0 to 9.0, and then (sharply) declined from 11.0 to 13.0. The reasons are that in strong acidic circumstances, the coiled and compressed shape of DOM inhibits the hydrophobic interaction, whereas in strong alkaline conditions, significant electrostatic repulsion reduces the sorption. This study reveals that the effects of DOM on the bioavailability of PPCPs are dependent on both pH and the specific compound involved.

Effects and Mechanism of Hyperbranched Phosphate Polycarboxylate Superplasticizers on Reducing Viscosity of Cement Paste.

The adsorption behavior and dispersing capability of hyperbranched phosphated polycarboxylate superplasticizers (PCEs) containing phosphate monoester and phosphate diester were investigated. The hyperbranched structures were constructed using a special monomer dimethylaminoethyl methacrylate (DMAMEA) to create the branches during the polymerization. Meanwhile, the polymer architectures were tailored by varying the content of phosphate monoester and phosphate diester in the backbone via free radical solution polymerization. In contrast to comb-like PCE, hyperbranched PCEs presented a weaker dispersion capability at w/c = 0.29, but with a lower water-to-cement ratio (w/c), the hyperbranched PCEs exhibited a better dispersion capability than the comb-like PCEs. The dynamic light scattering (DLS) and transmission electron microscope (TEM) analysis showed that the adsorption layer of hyperbranched PCEs were thicker than that of comb-like PCEs. A thicker adsorption layer thickness generated thinner diffusion water layer thickness. The increase of the free water amount due to the thinner water diffusion layer is the key mechanism for improving the dispersibility and decreasing the viscosity of cement paste.

Radiation chemical processes in the water layer on the surface of PuO2

Radiation chemical processes in the water layer on the surface of PuO2

Toward Modeling the Structure of Electrolytes at Charged Mineral Interfaces Using Classical Density Functional Theory.

The organization of water molecules and ions between charged mineral surfaces determines the stability of colloidal suspensions and the strength of phase-separated particulate gels. In this article, we assemble a density functional that measures the free energy due to the interaction of water molecules and ions in electric double layers. The model accounts for the finite size of the particles using fundamental measure theory, hydrogen-bonding between water molecules using Wertheim's statistical association theory, long-range dispersion interactions using Barker and Henderson's high-temperature expansion, electrostatic correlations using a functionalized mean-spherical approximation, and Coulomb forces through the Poisson equation. These contributions are shown to produce highly correlated structures, aptly rendering the layering of counterions and co-ions at highly charged surfaces and permitting the solvation of ions and surfaces to be measured by a combination of short-range associations and long-ranged attractions. The model is tested in a planar geometry near soft, charged surfaces to reproduce the structure of water near graphene and mica. For mica surfaces, explicitly representing the density of the outer oxygen layer of the exposed silica tetrahedra allows water molecules to hydrogen-bond to the solid. When electrostatic interactions are included, water molecules assume a hybrid character, being accounted for implicitly in the dielectric constant but explicitly otherwise. The disjoining pressure between approaching like-charged surfaces is calculated, demonstrating the model's ability to probe pressure oscillations that arise during the expulsion of ions and water layers from the interfacial gap and predict strong interattractive stresses that form at narrow interfacial spacing when the surface charge is overscreened. This interattractive stress arises not due to in-plane correlations under strong electrostatic coupling but due to the out-of-plane structuring of associating ions and water molecules.